Abstract

Nitroprusside is an important prebiotic molecule, thought to contribute to reaction pathways that lead to the production of amino acid chains (Mariani et al. [2018]). Nitroprusside can be made from Ferrocyanide photochemically. It has been found that the timescales for this reaction on Early Earth would have been between an order of days to months , making this route of abiotic production very useful in further prebiotic reaction networks and an important factor to consider when discussing the viability of life to evolve on a planet (Rimmer et al. [2021]). Here we investigate this reaction with a focus on constant and time varied radiation, meaning experimental runs involving the sample being subjected to a constant flux of UV light and runs with UV flux changing over time. FlareLab makes use of a broad band UV-Vis Laser Driven Light Source (LDLS), to experimentally simulate stellar irradiation and stellar flaring activity. The reasoning behind investigating flares is based on recent findings that have shown that M-dwarves are prone to flaring (G¨unther et al. [2020]). Flaring for M-dwarves is also shown to be the best way to get enough UV to an exoplanet’s surface for good yield of photochemical products (Ranjan et al. [2017]). With M-dwarves seen as the best stars to look at to detect small rocky planets, it is important to consider how flaring could effect the production of Nitroprusside and if there’s a discrepancy between assuming a constant irradiation of the surface or taking into account flaring.

We show that FlareLab can be used as a means of detecting the production of Nitroprusside in-situ during the irradiation period. We also compare the constant flux and variable flux regimes, and discuss the implications of these findings.