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SUMMARY:Harnessing Radicals and Carbenes To Enable Unconventional Reactivi
 ty - Prof. David Nagib\, The Ohio State University
DTSTART:20220915T150000Z
DTEND:20220915T160000Z
UID:TALK177575@talks.cam.ac.uk
CONTACT:Dr. Robert J. Phipps
DESCRIPTION:Radical chemistry can afford opposite or orthogonal reactivity
  to classic two-electron pathways. By developing radical chaperone strateg
 ies that merge open (1e-) and closed shell (2e-) processes\, we have harne
 ssed this complementary reactivity and imparted new types of chemo-\, regi
 o-\, and stereo- selectivity for remote\, double\, or reversed C-H and C-O
  functionalizations of alcohols\, amines\, and carbonyls. These radical ch
 aperone tools are continually being developed to streamline the synthesis 
 of complex\, medicinally relevant molecules and heterocycles.
LOCATION:Department of Chemistry\, Cambridge\, Unilever lecture theatre
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