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SUMMARY:From binary anionic P4 analogs to ternary intermetalloid clusters 
 - Stefanie Dehnen\, Philipps University Marburg
DTSTART:20180118T140000Z
DTEND:20180118T150000Z
UID:TALK95578@talks.cam.ac.uk
CONTACT:Sharon Connor
DESCRIPTION:Heterometallic cluster compounds are currently actively invest
 igated by many research groups\, leading from structural studies through f
 unctional analyses to the generation of innovative materials.[1\,2] Binary
  anionic P4 analogs\, [E142E152]2– and [E13E153]2– (E13 = Ga\, In\, Tl
 \; E14 = Ge\, Sn\, Pb\; E15 = As\, Sb\, Bi)\, hence binary tetrahedral Zin
 tl-anions\, proved to be useful synthetic tools in reactions with transiti
 on metal compounds for assembling ternary intermetalloid clusters [MxE13/1
 4yE14/15z]q–.[3\,4] The latter possess a large variety of different stru
 ctural motifs and corresponding electronic properties\, depending on the n
 ature of the involved elements.[5-8] Unprecedented\, non-classical structu
 res helped to gain deeper insight in the formation of such aggregates.[9.1
 0]\n  \nReferences:\n[1] S. Scharfe\, F. Kraus\, S. Stegmaier\, A. Schier\
 , T. F. Fässler\, Angew. Chem. Int. Ed. 2011\, 50\, 3630.\n[2] R.S.P. Tur
 bervill\, J.M. Goicoechea\, Chem. Rev. 2014\, 114\, 10807.\n[3] F. Lips\, 
 M. Hołyńska\, R. Clerac\, U. Linne\, I. Schellenberg\, R. Pöttgen\, F.W
 eigend\, S. Dehnen\, J. Am. Chem. Soc. 2012\, 134\, 1181.\n[4] B. Weinert\
 , S. Dehnen\, Struct. Bond. 2017\, 174\, 99.\n[5] B. Weinert\, F. Müller\
 , K. Harms\, S. Dehnen\, Angew. Chem. Int. Ed. 2014\, 53\, 11979.\n[6] R. 
 J. Wilson\, L. Broeckaert\, F. Spitzer\, F. Weigend\, S. Dehnen\, Angew. C
 hem. Int. Ed. 2016\, 54\, 11775.\n[7] N. Lichtenberger\, R. J. Wilson\, A.
  R. Eulenstein\, W. Massa\, R Clérac\, F. Weigend\, S. Dehnen\, J. Am. Ch
 em. Soc. 2016\, 138\, 9033.\n[8] N. Lichtenberger\, N. Spang\, A. Eichhöf
 er\, S. Dehnen\, Angew. Chem. Int. Ed. 2017\, 56\, 13253.\n[9] S. Mitzinge
 r\, L. Broeckaert\, W. Massa\, F. Weigend\, S. Dehnen\, Nat. Commun. 2016\
 , 7\, 10480.\n[10] R. J. Wilson\, S. Dehnen\, Angew. Chem. Int. Ed. 2017\,
  56\, 3098.\n
LOCATION:Wolfson Lecture Theatre\,  Department of Chemistry\, Lensfield Ro
 ad
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